M. Kontopoulou et al., AN EXPERIMENTAL-STUDY OF ROTATIONAL MOLDING OF POLYPROPYLENE POLYETHYLENE COPOLYMERS/, International polymer processing, 12(2), 1997, pp. 165-173
The objectives of this work are to assess the rotomoldability of rubbe
r toughened polypropylene resins and to investigate how resin properti
es can influence the process of rotational molding and the final part
quality. Four commercially available polypropylene/polyethylene copoly
mers were tested. The chemical composition and the powder, rheological
and thermal properties of the resins were determined. Rotational mold
ing experiments were carried out in a laboratory scale uniaxial machin
e which is capable of measuring internal mold temperature and which fa
cilitates the visual observation of various transitions in the cycle.
Impact and environmental stress clacking resistance tests, as well as
thickness distribution and density measurements were performed on the
rotomolded parts. It was found that increasing rubber content results
in an improvement of the impact properties which is counteracted by di
fficulties in processing, presence of bubbles and uneven surfaces.