U. Bangert et al., HIGHLY SPATIALLY-RESOLVED X-RAY-ANALYSIS OF SEMICONDUCTOR ALLOYS AND NANOSTRUCTURES IN A SCANNING-TRANSMISSION ELECTRON-MICROSCOPE, Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties, 74(6), 1996, pp. 1421-1437
X-ray analysis in a high-resolution scanning transmission electron mic
roscope is carried out on III-V compound and SixGe1-x quantum wells an
d quantum wires. Simulated X-ray profiles were obtained by convolving
the electron beam profile with a composition function. From best fits
with experimental data, quantitated composition profiles can be obtain
ed with nanometre resolution. Compositions in wells and wires are inho
mogeneous. Ahoy clusters tend to form in III-V compound quaternary qua
ntum well stacks. SixGe1-x quantum wells on patterned substrates show
strong compositional asymmetries along the growth direction and so do
quantum wires in both materials systems. In the case of the SixGe1-x s
ystem, aspects of the growth dynamics which lead to the observed compo
sitional behaviour are deduced.