We show that an induced s-wave harmonic in the superconducting gap of
an orthorhombic d(x2-y2) superconductor strongly affects the excitatio
n spectrum near a twinning plane. In particular, it yields bound state
s of zero energy with areal density proportional to the relative weigh
t of the s-wave component. An unusual scattering process responsible f
or the thermal conductivity across the twin boundary at low temperatur
es is also identified.