CRYSTAL-STRUCTURE OF N,N,N',N'-TETRAISOPR OPYL-P-PHENYLENE-DIAMMONIUMDICHLORIDE AND TRAISOPROPYL-P-PHENYLENE-BIS(TETRACHLOROALUMINATE)

Authors
NATHER C GOBEL I BOCK H HERDTWECK E
Citation
C. Nather et al., CRYSTAL-STRUCTURE OF N,N,N',N'-TETRAISOPR OPYL-P-PHENYLENE-DIAMMONIUMDICHLORIDE AND TRAISOPROPYL-P-PHENYLENE-BIS(TETRACHLOROALUMINATE), Monatshefte fuer Chemie, 128(8-9), 1997, pp. 841-848
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Monatshefte fuer Chemie → ACNP
ISSN journal
00269247
Volume
128
Issue
8-9
Year of publication
1997
Pages
841 - 848
Database
ISI
SICI code
0026-9247(1997)128:8-9<841:CONO>2.0.ZU;2-#
Abstract
Protonation of the sterically overcrowded N,N,N',N'-tetraisopropyl-p-p henylenediamine leads to a significant shortening of the C-N bond leng ths of 7 pm as well as to a widening of the phenyl ipso-angle to 122 d egrees. All structural changes can be attributed to the twisted diisop ropylammonium substituents and their electron acceptor properties.