CHRONOPOTENTIOMETRIC STUDY OF EC MECHANISM DURING THE FIRST CYCLE OF ALTERNATING-CURRENT

Authors
MOLINA A MARTINEZORTIZ F RUIZ R LOPEZTENES M
Citation
A. Molina et al., CHRONOPOTENTIOMETRIC STUDY OF EC MECHANISM DURING THE FIRST CYCLE OF ALTERNATING-CURRENT, Collection of Czechoslovak Chemical Communications, 62(5), 1997, pp. 709-728
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
62
Issue
5
Year of publication
1997
Pages
709 - 728
Database
ISI
SICI code
0010-0765(1997)62:5<709:CSOEMD>2.0.ZU;2-8
Abstract
The theoretical approach to the application of the first period of a s inusoidal current at static and dynamic spherical electrodes for study of EC mechanism is presented. Methods for determining heterogeneous a nd homogeneous kinetic parameters are proposed. In order to check theo retical result, the rate of benzidine rearrangement was evaluated from transition time measurements.