REACTION OF 4-OXOCHROMENE-3-CARBOXALDEHYDES WITH PRIMARY AMIDES AND BENZOTRIAZOLE OR 1H-1,2,4-TRIAZOLE

Citation
H. Stankovicova et al., REACTION OF 4-OXOCHROMENE-3-CARBOXALDEHYDES WITH PRIMARY AMIDES AND BENZOTRIAZOLE OR 1H-1,2,4-TRIAZOLE, Collection of Czechoslovak Chemical Communications, 62(5), 1997, pp. 781-790
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
62
Issue
5
Year of publication
1997
Pages
781 - 790
Database
ISI
SICI code
0010-0765(1997)62:5<781:RO4WPA>2.0.ZU;2-Z
Abstract
-oxochromen-3-yl)(1,2,4-triazol-3-yl)methyl]amides 5 and uted-4-oxochr omen-3-yl)(benzotriazol-1-yl)methyl]a 6 were prepared by the reaction of 6-substituted 4-oxochromene-3-carboxaldehydes 1 with primary amides and 1H-1,2,4-triazole or 1H-benzotriazole. 6-Substituted 3-[hydroxy(1 ,2,4-triazol-1-yl)methyl]chromen-4-one 2 and 6-substituted 3-[hydroxy( benzotriazol-1-yl)methyl]chromen-4-one 3 were isolated as stable inter mediates of these reactions. Beneficial effect of microwave irradiatio n on length of reaction time was observed. Some reactions of these der ivatives with O, S, and N nucleophiles are described.