Z. Belohlav et al., APPLICATION OF RANDOM-SEARCH ALGORITHM FOR REGRESSION-ANALYSIS OF CATALYTIC HYDROGENATIONS, Canadian journal of chemical engineering, 75(4), 1997, pp. 735-742
A short review of the works concerning parameter estimation in kinetic
experiments was performed. An adaptive random search algorithm was ap
plied to evaluate the parameters and parameter confidence intervals of
Langmuir-Hinshelwood models. The kinetic parameters were determined u
sing the Box - Draper criterion. The parameter confidence regions were
found by using the likelihood ratio. Three heterogeneously catalyzed
hydrogenations were studied.