SORPTION OF AMMONIA, METHYLAMINE AND METHANOL BY THE P3 POLYMORPH OF GOSSYPOL - SYNTHESIS OF UNSYMMETRICAL MONOAMINE DERIVATIVES OF GOSSYPOL BY A SOLID-STATE REACTION

Authors
TALIPOV SA MANAKOV A IBRAGIMOV BT LIPKOWSKI J TILJAKOV ZG
Citation
Sa. Talipov et al., SORPTION OF AMMONIA, METHYLAMINE AND METHANOL BY THE P3 POLYMORPH OF GOSSYPOL - SYNTHESIS OF UNSYMMETRICAL MONOAMINE DERIVATIVES OF GOSSYPOL BY A SOLID-STATE REACTION, Journal of inclusion phenomena and molecular recognition in chemistry, 29(1), 1997, pp. 33-39
Citations number
12
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
29
Issue
1
Year of publication
1997
Pages
33 - 39
Database
ISI
SICI code
0923-0750(1997)29:1<33:SOAMAM>2.0.ZU;2-A
Abstract
The P3 polymorph of gossypol has wide, empty channels and strongly abs orbs linear amines. One of the two gossypol aldehyde groups is located near the channel wall. This situation allows reaction of the amines w ith half of a gossypol molecule, yielding unsymmetric monoaminoderivat ives of gossypol in high yield and by a simple, solid-state method.