REACTIONS OF (Z)-ALPHA,BETA-DIDEHYDROAMINO ALDEHYDES WITH ETHYL DIETHYLPHOSPHONOACETATE, ETHYL-ACETATE, AND TRIMETHYLSILYL CYANIDE

Authors
NAKAMURA Y SHIN CG
Citation
Y. Nakamura et Cg. Shin, REACTIONS OF (Z)-ALPHA,BETA-DIDEHYDROAMINO ALDEHYDES WITH ETHYL DIETHYLPHOSPHONOACETATE, ETHYL-ACETATE, AND TRIMETHYLSILYL CYANIDE, Synthesis, (6), 1994, pp. 552-554
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
6
Year of publication
1994
Pages
552 - 554
Database
ISI
SICI code
0039-7881(1994):6<552:RO(AWE>2.0.ZU;2-Z
Abstract
In order to explore the reactivity of (Z)-alpha,beta-didehydroamino al dehydes, Wittig-Horner reaction with ethyl diethylphosphonoacetate, al dol condensation with ethyl acetate, and cyanohydrin reaction with tri methylsilyl cyanide were tried successfully to give the corresponding dienocarboxylate, enolcarboxylate, and cyanohydrin derivatives, respec tively, in good yields.