S. Bhattacharyya et al., ENHANCEMENT IN STRENGTH AND TOUGHNESS OF AL2O3 DUE TO DISSOLUTION OF CARBON, Bulletin of Materials Science, 20(5), 1997, pp. 685-691
An improvement in fracture toughness and strength is observed in carbo
n atmosphere sintered alumina on reheating the sintered samples in air
at 1200 degrees C. SEM photographs show the presence of secondary pre
cipitate particles at grain boundaries of the sintered samples, which
disappear after reheating in air. Infrared spectroscopy indicates that
the C-O bond intensity increases on reheating in air. An AES/XPS stud
y reveals that carbon enters the alumina lattice on reheating. These r
esults lead to the conclusion that the enhanced fracture toughness and
strength are related to the dissolution of precipitates and consequen
t dissolution of carbon in alumina lattice.