Photoluminescent (PL) properties of heavily carbon- and zinc-doped GaA
s were investigated for concentration from 8 X 10(17) to 2.3 x 10(20)
cm-3 and temperature from 300 K to 20 K. Both a band-to-band (B, B) pe
ak and a band-to-acceptor (e, A) peak appeared at 300 K for the heavil
y p-type-doped GaAs PL spectra, even in degenerated GaAs. The variatio
n of the intensities of the (e, A) peak and (B, B) peak with concentra
tion and temperature was investigated, and the change in position of t
he two peaks at various concentrations and temperatures was observed.
The rapid increase in linewidth with increasing concentration due to t
he appearance of a shoulder peak was also studied; this behavior is di
fferent from that of the shoulder peak in the PL spectrum from Zn-dope
d crystal.