I. Mukhopadhyay et al., HIGH-RESOLUTION SPECTROSCOPY OF METHANOL-D-3 - ASSIGNMENTS AND PREDICTIONS OF OPTICALLY PUMPED FAR-INFRARED LASER LINES, Journal of the Optical Society of America. B, Optical physics, 14(9), 1997, pp. 2227-2237
The results of high-resolution Fourier-transform infrared and far-infr
ared spectroscopic studies have been applied to the analysis and predi
ction of optically pumped far-infrared laser emission for 11 transitio
n systems of the CD3OH isotopomer of methanol. The assignments are sup
ported by the formation of closed transition combination loops that co
nfirm the spectroscopic assignments and yield calculated far-infrared
laser wave numbers to the spectroscopic accuracy of order +/-0.0005 cm
(-1). This represents a substantial improvement over customary wavelen
gth measurements. Four of ther systems involve the strong asymmetry mi
xing known to occur between K = 0 and K = 2 E-1 levels, which is discu
ssed and partially analyzed. Several inconsistencies are noted between
previous proposed assignments in the literature, which were based pri
marily on calculated energies and infrared wave numbers, and our new s
pectroscopic data. (C) 1997 Optical Society of America.