N. Saito et al., SUSCEPTIBILITY OF SENSITIZED TYPE-304 STAINLESS-STEEL TO INTERGRANULAR STRESS-CORROSION CRACKING IN SIMULATED BOILING-WATER REACTOR ENVIRONMENTS, Corrosion, 53(7), 1997, pp. 537-545
Slow strain rate tests (SSRT) were conducted to evaluate the mitigatin
g effect of hydrogen water chemistry (HWC) on intergranular stress cor
rosion cracking (IGSCC) of sensitized type 304 (UNS S30400) stainless
steel (SS) used for in-reactor components of boiling-water reactors (B
WR). The in-reactor environment was simulated by controlling water che
mistry parameters such as dissolved oxygen (DO), dissolved hydrogen (D
H), hydrogen peroxide (H2O2), and corrosion potential (E-corr). Effect
s of the products of water radiolysis on SCC behavior mere examined in
the presence of a gamma-radiation field. IGSCC susceptibility of sens
itized type 304 SS decreased with decreasing concentrations of DO and
H2O2, which suggested IGSCC of sensitized type 304 SS could be mitigat
ed even in the in-reactor environment under HWC conditions. IGSCC susc
eptibility clearly was dependent upon E-corr, as controlled by the con
centrations of stable radiolytic products (e.g., O-2, H2O2, and H-2).
regardless of short-lived radicals generated by gamma-radiation.