THE ROLE OF STRUCTURAL TRANSFORMATIONS IN MAGNETIC-BEHAVIOR OF FLUOROSILICATES OF 3D TRANSITION-METALS

Citation
Sk. Asadov et al., THE ROLE OF STRUCTURAL TRANSFORMATIONS IN MAGNETIC-BEHAVIOR OF FLUOROSILICATES OF 3D TRANSITION-METALS, Journal of physics. Condensed matter, 9(34), 1997, pp. 7161-7171
Citations number
15
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09538984
Volume
9
Issue
34
Year of publication
1997
Pages
7161 - 7171
Database
ISI
SICI code
0953-8984(1997)9:34<7161:TROSTI>2.0.ZU;2-F
Abstract
The stability of the structural phases in the fluorosilicate hexahydra tes of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The resu lts are generalized in the form of a P-T phase diagram of crystal stat es. The triple points, new high-pressure phases and wide ranges of met astable states between them have been discovered. The correspondence b etween structural and magnetic P-T phase diagrams of the series is est ablished.