EQUILIBRIUM STUDIES OF ALKYLTIN(IV) COMPLEXES WITH D-GLUCOSAMINE

Authors
SHOUKRY MM ELMEDANI SM
Citation
Mm. Shoukry et Sm. Elmedani, EQUILIBRIUM STUDIES OF ALKYLTIN(IV) COMPLEXES WITH D-GLUCOSAMINE, Collection of Czechoslovak Chemical Communications, 62(7), 1997, pp. 1023-1028
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
62
Issue
7
Year of publication
1997
Pages
1023 - 1028
Database
ISI
SICI code
0010-0765(1997)62:7<1023:ESOACW>2.0.ZU;2-0
Abstract
The acid-base and complex-formation equilibria involving glucosamine a nd its complexes with alkyltin(IV) chlorides have been studied by pote ntiometric technique. The results prove to a formation of 1 : 1 comple x with trialkyltin(IV) and both 1 : 1 and 1 : 2 complexes with dialkyl tin(IV) species. The stability constants in water were determined, the effects of temperature (from 15 to 35 degrees C) and ethanol (up to 8 8 vol.%) was studied and the speciation of the complexes was resolved.