We report on the interfacial intermixing of ultrathin Co films on a Cu
(001) single crystal, two materials that are immiscible in the bulk. W
ith increasing deposition rate we find a crossover from layer-by-layer
to bilayer growth due to a hindered diffusion from the first layer to
the substrate. Above two monolayers, growth proceeds In a layer-by-la
yer fashion. These effects are explained in terms of surface free ener
gies. (C) 1997 Elsevier Science B.V.