LATTICE-GAS MODEL FOR THE ADSORPTION OF GUANIDINIUM NITRATE AT THE MERCURY-WATER INTERFACE

Authors
BELKASRI AK HUCKABY DA BLUM L
Citation
Ak. Belkasri et al., LATTICE-GAS MODEL FOR THE ADSORPTION OF GUANIDINIUM NITRATE AT THE MERCURY-WATER INTERFACE, Langmuir, 13(18), 1997, pp. 4887-4891
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Langmuir → ACNP
ISSN journal
07437463
Volume
13
Issue
18
Year of publication
1997
Pages
4887 - 4891
Database
ISI
SICI code
0743-7463(1997)13:18<4887:LMFTAO>2.0.ZU;2-G
Abstract
A lattice gas of trigonal-planar cations and anions on the triangular lattice is constructed to model the adsorption of guanidinium nitrate at the mercury-water interface. For physically realistic intermolecula r interactions and electrochemical potentials, the Pirogov-Sinai theor y is used to rigorously prove the presence at low temperatures of a he xagonal hydrogen-bonded phase in the model. This phase is consistent w ith the monolayer structure recently proposed on the basis of experime nts.