PREPARATION AND CRYSTAL-STRUCTURE OF THE NEW IONIC BIS-[HYDRAZIDO]-MOLYBDENUM COMPLEX [MO(NNPH2)(2)(ACAC)(PPH3)(2)]-(OTF)

Authors
MANZUR C CARRILLO D BAGGIO R GARLAND MT
Citation
C. Manzur et al., PREPARATION AND CRYSTAL-STRUCTURE OF THE NEW IONIC BIS-[HYDRAZIDO]-MOLYBDENUM COMPLEX [MO(NNPH2)(2)(ACAC)(PPH3)(2)]-(OTF), Journal of chemical crystallography, 27(6), 1997, pp. 339-342
Citations number
20
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
27
Issue
6
Year of publication
1997
Pages
339 - 342
Database
ISI
SICI code
1074-1542(1997)27:6<339:PACOTN>2.0.ZU;2-L
Abstract
The title compound [Mo(NNPh2)(2)(acac)(PPh3)(2)]+OTf-,Mr = 1233.1, cry stallizes in the triclinic space group P (1) over bar, with a = 12.881 (4), b = 13.795(3), c = 17.160(5)Angstrom, alpha = 90.95(1), beta = 91 .31(1), gamma = 103.53(1)degrees, and Z = 2. The structure was solved by Patterson methods, and refined with some difficulties due to extens ive disorder in the counterion. The Mo ion is hexacoordinated in an oc tahedral environment, with two O and two N defining the basal plane, a nd two P atoms in the apical sites.