P. Ding et Wk. Yuan, INDUCTIVELY HEATED CVD REACTOR FOR COATING TIN FILM ONTO A TUNGSTEN CARBIDE SURFACE, Chemical Engineering Science, 49(13), 1994, pp. 2153-2161
In an rf inductively heated quartz reactor, high-quality TiN film can
be deposited onto a hard alloy cutting tool surface. Preferable operat
ing conditions are found by experiments. Strong natural convection of
gas and point-to-point temperature difference occur between the substr
ate and the reactor wall. Four second-order partial differential equat
ions (PDE) have been set up to describe flow pattern, temperature dist
ribution, and deposition rate. Galerkin's finite element method is app
lied for this two-dimensional problem. The domain is split into 262 qu
adrangle elements with 909 nodes. For a cold-wall reactor, the streaml
ines and isotherms are shown. An upward flow above the substrate causi
ng a nonuniform deposition rate on the horizontal surface matches the
authors' experiments. Experiments for TiN deposition rates under diffe
rent TiCl4 partial pressures are carried out to check computer simulat
ion results.