THE NEW EXPERIMENTAL-EVIDENCE FOR PROTONA TIONAL SITE OF HETEROPOLY BLUE - INVESTIGATION BY IN-SITU FTIR SPECTROELECTROCHEMICAL METHOD

Authors
ZHANG SY SUN HR XING YH YANG GY XU JQ
Citation
Sy. Zhang et al., THE NEW EXPERIMENTAL-EVIDENCE FOR PROTONA TIONAL SITE OF HETEROPOLY BLUE - INVESTIGATION BY IN-SITU FTIR SPECTROELECTROCHEMICAL METHOD, Gaodeng xuexiao huaxue xuebao, 18(6), 1997, pp. 955-957
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
6
Year of publication
1997
Pages
955 - 957
Database
ISI
SICI code
0251-0790(1997)18:6<955:TNEFPT>2.0.ZU;2-E
Abstract
The electrochemical reduction processes of heteropolyanion PMo12O403- in protonic media were investigated by in-situ FTIR spectroelectrochem ical method. Experimental results indicated that the protonational sit e of electroreduction product HnPMo12O403- (n=2, 4, 6, 8) was on bridg e oxygen atom, The infrared characteristic absorption peaks of Mo = O double bound shift to higher frequence after electroreduction of heter opolyanion PMo12O403-. This result can be interpreted from the viewpoi nt of induction effect of proton.