M. Erbudak et al., SURFACE PHASE-TRANSITIONS DURING MARTENSITIC TRANSFORMATIONS OF SINGLE-CRYSTAL CO, Physical review letters, 79(10), 1997, pp. 1893-1896
The phase transitions of close-packed surfaces that accompany the mart
ensitic transformations between the hexagonal close-packed and face-ce
ntered cubic structures of single-crystal Co are observed in real spac
e and in real time with secondary-electron imaging. Simultaneous measu
rement of the bulk resistivity is used to identify the onset of the bu
lk transformation. The surface transitions show a broader thermal hyst
eresis than that of the resistivity, indicating that the martensitic t
ransformation is initiated in the bulk and proceeds slowly to the surf
ace.