TRANSITION-METAL-SUBSTITUTED ACYLPHOSPHANES AND PHOSPHAALKENES .35. UNPRECEDENTED COUPLING OF A TRANSITION-METAL CARBYNE AND A METHYLENE PHOSPHANE MOIETY - STRUCTURE OF [TP'(CO)(2)W-CP=C(NET2)(2)] [TP'=HB(3,5-ME2HC3N2)(3)]

Authors
WEBER L DEMBECK G BOESE R BLASER D
Citation
L. Weber et al., TRANSITION-METAL-SUBSTITUTED ACYLPHOSPHANES AND PHOSPHAALKENES .35. UNPRECEDENTED COUPLING OF A TRANSITION-METAL CARBYNE AND A METHYLENE PHOSPHANE MOIETY - STRUCTURE OF [TP'(CO)(2)W-CP=C(NET2)(2)] [TP'=HB(3,5-ME2HC3N2)(3)], Chemische Berichte, 130(9), 1997, pp. 1305-1308
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
130
Issue
9
Year of publication
1997
Pages
1305 - 1308
Database
ISI
SICI code
0009-2940(1997)130:9<1305:TAAP.U>2.0.ZU;2-5
Abstract
Condensation of [Tp'(CO)(2)M = CCl] [1: M = Mo; 2: W; Tp' = HB(3,5-Me2 HC3N2)(3)] with the inverse phosphaalkenes Me3SiP = C(NR2)(2) (3a: R = Me; 3b: Et) affords the novel phosphaalkenyl carbyne complexes [Tp'(C O)2M = C-P = C(NR2)(2)] (4a, b) (M = Mo; R = Me, Et) and 5a, b (M = W; R = Me, Et), which have been characterized by IR, H-1-, C-13- and P-3 1-NMR spectroscopy. In addition, the molecular structure of 5b has bee n elucidated by a single-crystal X-ray structure determination.