SYNTHESIS AND PROPERTIES OF TRIS(OCTAETHYLPORPHYRIN)S CONNECTED WITH VINYLENE GROUPS

Authors
HIGUCHI H SHIMIZU K TAKEUCHI M OJIMA J SUGIURA KI SAKATA Y
Citation
H. Higuchi et al., SYNTHESIS AND PROPERTIES OF TRIS(OCTAETHYLPORPHYRIN)S CONNECTED WITH VINYLENE GROUPS, Bulletin of the Chemical Society of Japan, 70(8), 1997, pp. 1923-1933
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
70
Issue
8
Year of publication
1997
Pages
1923 - 1933
Database
ISI
SICI code
0009-2673(1997)70:8<1923:SAPOTC>2.0.ZU;2-X
Abstract
Tris(octaethylporphyrin)s, in which two octaethylporphyrin (OEP) rings are connected with vinylene groups at alpha,gamma- and alpha,beta-mes o positions of the central OEP ring, were synthesized. The tris(OEP)s have similar conformational and configurational structures to the corr esponding vinylene group-connected bis(OEP). Examination of both (HNMR )-H-1 and electronic absorption spectra of the tris(OEP)s showed the b ehavior reflecting the highly symmetrical structure and the mutual int eraction between the three OEP rings through the vinylene linkages.