KINETICS AND MECHANISM OF THE REACTION OF XENON TETROXIDE WITH HYDROGEN

Authors
ALEINIKOV NN VASILEV GK KASHTANOV SA MAKAROV EF CHERNYSHEV YA
Citation
Nn. Aleinikov et al., KINETICS AND MECHANISM OF THE REACTION OF XENON TETROXIDE WITH HYDROGEN, Kinetics and catalysis, 38(4), 1997, pp. 464-469
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
4
Year of publication
1997
Pages
464 - 469
Database
ISI
SICI code
0023-1584(1997)38:4<464:KAMOTR>2.0.ZU;2-T
Abstract
The dependence of the rate of the reaction of XeO4 with Hz at room tem perature on the concentrations of the reagents H-2 and XeO4 and diluen t gases He, O-2, and CO2 is investigated. A reaction mechanism that in cludes the stages involving vibrationally excited (OH)-O-. radicals is proposed to explain different effects of additives.