Many solar systems in the universe may be expected to contain rocky pl
anets that have accreted organic compounds. These compounds are likely
to be universally found. In addition, the chemistry of sulfur, phosph
orous, and iron is likely to dominate energy transductions and monomer
activation, leading to the eventual emergence of polymers. Proteins a
nd polynucleotides provide living matter with function, structure, and
information. The conceptual puzzle regarding their emergence is discu
ssed. The fitness of various elements to serve various roles is analyz
ed from the viewpoint of electron orbitals. Elements with d orbitals a
re of central importance.