Our investigations focus on low-temperature luminescence experiments o
n a set of type-II GaAs/AlAs multiple-quantum-well (MQW) samples grown
by low-pressure metal-organic vapor-phase epitaxy. The layered struct
ures consists of 50 periods of either 2 monolayers (ML), 4, 5, 6, or 7
ML GaAs embedded in 28 ML AlAs. For (001) GaAs substrates, 6 degrees
misoriented towards the nearest (111) plane of group-V atoms, monolaye
r steps at the AlAs/GaAs interfaces with regular terrace widths (2.7 n
m) can be seen by high-resolution transmission-electron microscopy. In
the photoluminescence spectra of these MQW samples, type-I luminescen
ce is found to be dominant even at room temperature. The peak waveleng
th of the type-I emission depends strongly on the GaAs layer thickness
; it ranges from about 620-440 nm. The intense type-I emission seems t
o be connected with the interface peculiarities. Our astonishing obser
vation might be explained as follows: (i) The perfect interface struct
ure pl events the loss of photoexcited carriers from GaAs layers to th
e surrounding AlAs materials, i.e., the energy loss by optical-phonon
scattering is reduced. (ii) For our well thicknesses two-dimensional (
2D) phonons must be coupled with 3D electrons leading also to a reduct
ion of the electron-phonon interaction. (iii) The regular interface st
eps should favor a coherent interaction (quantum interferences) of exc
itons and/or electrons confined in the GaAs wells with energetically r
esonant continuum states of the AlAs barriers. The experimentally obse
rved optical transition energies of the type-I and type-II recombinati
on are compared with model calculations applying an effective-mass app
roach and empirical tight-binding Green's-function scheme.