Mn-nodule is one of the most important deep sea mineral resources to b
e explored and exploited in the next century. Analytical quality contr
ol based on this kind of Certified Reference Materials (CRMs) is there
fore necessary. In the present work, nearly 30 elements in two Chinese
Mn nodule Reference Materials (RMs), GSPN-2 and GSPN-3, were determin
ed using extended Kg-relative comparison NAA technique, developed in o
ur laboratory. The unique features of this work include: (1) high accu
racy obtained by the internal validation function of our technique; (2
) extensive determinable elements obtained by the hybrid nature of our
software and (3) neutron flux self-shielding corrections.