SYNTHESIS OF CHIRAL 2-ARYLPROPENOIC ESTERS BY THE PALLADIUM-CATALYZEDCARBONYLATION OF ARYLACETYLENES

Authors
MONTEIRO AL LANDO VR GASPARINI V
Citation
Al. Monteiro et al., SYNTHESIS OF CHIRAL 2-ARYLPROPENOIC ESTERS BY THE PALLADIUM-CATALYZEDCARBONYLATION OF ARYLACETYLENES, Synthetic communications, 27(20), 1997, pp. 3605-3611
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
20
Year of publication
1997
Pages
3605 - 3611
Database
ISI
SICI code
0039-7911(1997)27:20<3605:SOC2EB>2.0.ZU;2-0
Abstract
A simple method is described for the synthesis of chiral 2-arylpropeno ic esters by carbonylation of arylacetylenes in the presence of chiral alcohols catalyzed by palladium complexes under mild conditions (10 a tm, 100 degrees C, 2h) with high yields.