CATALYTIC CONVERSIONS IN WATER .6. A NOVEL BIPHASIC HYDROCARBOXYLATION OF OLEFINS CATALYZED BY PALLADIUM TPPTS COMPLEXES (TPPTS=P(C6H4-M-SO3NA)(3))

Authors
PAPADOGIANAKIS G VERSPUI G MAAT L SHELDON RA
Citation
G. Papadogianakis et al., CATALYTIC CONVERSIONS IN WATER .6. A NOVEL BIPHASIC HYDROCARBOXYLATION OF OLEFINS CATALYZED BY PALLADIUM TPPTS COMPLEXES (TPPTS=P(C6H4-M-SO3NA)(3)), Catalysis letters, 47(1), 1997, pp. 43-46
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
47
Issue
1
Year of publication
1997
Pages
43 - 46
Database
ISI
SICI code
1011-372X(1997)47:1<43:CCIW.A>2.0.ZU;2-L
Abstract
Exceptionally high catalytic activities (TOF > 2500 h(-1)) have been a chieved in the biphasic hydrocarboxylation of propene catalysed by wat er-soluble Pd/TPPTS complexes. The activity was even higher than that exhibited by organic-soluble Pd/PPh3 systems. This contrasts with the general perception that biphasic catalysis normally exhibits lower rat es compared to analogous reactions in organic media. The hydrocarboxyl ation of 4-isobutylstyrene to ibuprofen and of styrene in a two-phase system is also reported.