A. Angelova et al., DOMAIN PATTERN INSTABILITY OF A LIPID MONOLAYER INDUCED BY ADSORPTIONDESORPTION OF A CYANINE DYE/, Thin solid films, 285, 1996, pp. 85-89
Brewster angle microscopy (BAM) is applied for studying the in-plane m
orphology of a cationic lipid monolayer and its interaction with a nov
el, water-soluble, J-aggregate forming, negatively charged carbocyanin
e dye. A methodology of monolayer compression/recompression is followe
d to influence the dye crystallization upon adsorption from an aqueous
subsolution at a charged interface. Crystalline domains of a dendriti
c type are observed in the lipid monolayer compressed on a pure water
subphase. Dye aggregation and crystalline nucleation is established by
means of BAM for 2D lipid densities corresponding to the onset of the
main phase transition of the composite monolayer. Subphase conditions
, which prevent the nucleation of lipid 2D crystalline phase domains,
are found to not favor dye crystallization at the interface, Dye adsor
ption and aggregation is established to be partially irreversible upon
monolayer decompression. Dye desorption is related to the observation
of stripe-like objects in the lipid monolayer, developing undulation
instability, which produces non-equilibrium 2D labyrinthine patterns w
ith time.