Hj. Herbert et J. Monig, COMPLEX-REACTIONS BETWEEN TOXIC-CHEMICAL WASTES AND HIGH SALINE SOLUTIONS TAKING INTO ACCOUNT UNDERGROUND REPOSITORY CONDITIONS, Geologische Rundschau, 86(2), 1997, pp. 389-403
The complex reactions between high saline solutions and toxic chemical
wastes were investigated by means of laboratory experiments and geoch
emical modelling. The specific boundary conditions of an underground r
epository in salt formations were taken into account. In order to dete
rmine the chemical equilibrium compositions of the resulting solutions
a new leaching procedure was developed and successfully employed with
several toxic wastes. The results for a fly ash waste stemming from a
glass smelting furnace are given in detail. Zinc and cadmium are the
two most prominent heavy metals, that accumulate significantly in the
leachates. In order to gain an insight into the complex dissolution an
d precipitation processes in such multi-component systems, geochemical
modelling was performed using the program code EQ3/6 and the Fitter f
ormalism for calculating the activity coefficients. The thermodynamic
database used was extended and Fitter coefficients for Zn and Cd in hi
gh saline solutions were derived from literature data and added to the
database. The results of the geochemical modelling of the investigate
d reactions were in good agreement with the experimental data. On this
basis the maximum concentrations that can be leached from the investi
gated fly ash into a Mg-rich saline solution, that is typical for a sa
lt repository in Northern Germany, are predicted to be 0,181 mol/kg H2
O zinc and 0,00317 mol/kg H2O cadmium, respectively.