B. Bansal et al., EFFECT OF SUSPENDED PARTICLES ON CRYSTALLIZATION FOULING IN PLATE HEAT-EXCHANGERS, Journal of heat transfer, 119(3), 1997, pp. 568-574
The presence of suspended particles in solutions significantly affects
the crystallization rate. This study investigates the effects of calc
ium sulphate (crystallizing) particles and alumina (noncrystallizing)
particles on calcium sulphate crystallization fouling in a plate heat
exchanger. Calcium sulphate particles are formed during the preparatio
n of calcium sulphate solution due to breakage of calcium sulphate cry
stals growing on the heat transfer surface. These suspended particles
settle on the heat transfer surface and act as nuclei. The availabilit
y of extra nucleation sites increases the crystallization rate signifi
cantly. These particles can be removed with a filter, and the removal
of the particles prevents this extra assistance available for crystall
ization. Therefore, the crystallization rate is reduced markedly. Alum
ina particles were purposely added during the preparation of calcium s
ulphate solutions. These particles attach loosely to the heat transfer
surface compared with crystalline deposits which adhere strongly. The
refore, calcium sulphate crystals growing on these particles are remov
ed easily. Also, alumina particles settling on the growth faces of cal
cium sulphate crystals may act as a distorting agent. This slows down
the growth of the crystals.