SYNTHESIS AND X-BAND EPR-SPECTRA OF BINARY AND TERNARY COMPLEXES OF COPPER(II) WITH SALICYLIDENEANTHRANILIC ACID AND IMIDAZOLES

Authors
PATEL RN PANDEYA KB
Citation
Rn. Patel et Kb. Pandeya, SYNTHESIS AND X-BAND EPR-SPECTRA OF BINARY AND TERNARY COMPLEXES OF COPPER(II) WITH SALICYLIDENEANTHRANILIC ACID AND IMIDAZOLES, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(8), 1997, pp. 1149-1157
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
27
Issue
8
Year of publication
1997
Pages
1149 - 1157
Database
ISI
SICI code
0094-5714(1997)27:8<1149:SAXEOB>2.0.ZU;2-I
Abstract
The synthesis and EPR spectra of some binary and ternary complexes of copper(II) with a terdentate ligand, salicylideneanthranilic acid (H(2 )SAA) and some monodentate imidazoles viz. imidazole (im) and 2-ethyli midazole (e-im), are described. The binary complex with copper(II) and salicylideneanthranilic acid shows a subnormal magnetic moment and EP R spectra for spin-spin interaction. The zero-field splitting paramete r D has been evaluated as 190 G and the copper-copper distance as 5.22 7 Angstrom. The ternary complexes show magnetic moments and EPR spectr a which suggest a distorted tetrahedral geometry around copper(II).