SYNTHESIS AND CHARACTERIZATION OF AMIDO AND ROSYL[TRIS(3,5-DIMETHYLPYRAZOLYL)BORATO]MOLYBDENUM COMPLEXES

Authors
TOPALOGLU I MCCLEVERTY JA
Citation
I. Topaloglu et Ja. Mccleverty, SYNTHESIS AND CHARACTERIZATION OF AMIDO AND ROSYL[TRIS(3,5-DIMETHYLPYRAZOLYL)BORATO]MOLYBDENUM COMPLEXES, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(8), 1997, pp. 1205-1217
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
27
Issue
8
Year of publication
1997
Pages
1205 - 1217
Database
ISI
SICI code
0094-5714(1997)27:8<1205:SACOAA>2.0.ZU;2-4
Abstract
The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] was prep ared by treating [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl-2] with an excess of a mmonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)(3)}-(NO)(NH2 )(NHR)] (R = Me, Et, Pr-(n) under bar and Bu-(n) under bar) were obtai ned by the reaction of [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] with the a ppropriate primary amines. The IR and H-1 NMR spectra of the new compl exes were investigated.