ALKYL PHENYLGLYOXYLATES AS RADICAL PHOTOINITIATORS CREATING NEGATIVE PHOTOIMAGES

Authors
HU SK NECKERS DC
Citation
Sk. Hu et Dc. Neckers, ALKYL PHENYLGLYOXYLATES AS RADICAL PHOTOINITIATORS CREATING NEGATIVE PHOTOIMAGES, Journal of materials chemistry, 7(9), 1997, pp. 1737-1740
Citations number
26
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
7
Issue
9
Year of publication
1997
Pages
1737 - 1740
Database
ISI
SICI code
0959-9428(1997)7:9<1737:APARPC>2.0.ZU;2-W
Abstract
Alkyl phenylglyoxylates are shown to be efficient photoinitiators for acrylate polymerization. Benzoyl and phenyl radicals derived from inte rmolecular hydrogen abstraction are the initiating species. A negative photoimage system was developed based on this observation. The imagin g material consists of a polymeric phenylglyoxylate initiator and to-b e-crosslinked diacrylate monomers. The contrast and sensitivity of thi s system have been measured.