SYNTHESIS OF 1,2-FUSED INDOLES BY RADICAL CYCLIZATION

Citation
Cj. Moody et Cl. Norton, SYNTHESIS OF 1,2-FUSED INDOLES BY RADICAL CYCLIZATION, Journal of the Chemical Society. Perkin transactions. I, (17), 1997, pp. 2639-2643
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
17
Year of publication
1997
Pages
2639 - 2643
Database
ISI
SICI code
0300-922X(1997):17<2639:SO1IBR>2.0.ZU;2-#
Abstract
Treatment of the 1-(omega-iodoalkyl)indole-3-carbaldehydes 8-13 with t ributyltin hydride and AIBN results in radical cyclisation to give the 1,2-fused indoles 14-19 containing five-, six-and seven-membered ring s, The tetrahydropyridoindole 18 is converted into the indolequinone 2 3.