SHORT-RANGE SOLVATION OF PROTON-TRANSFER COMPLEXES BY 2,2-DIMETHYL-1,3-DIOXANE AND TRIOXANE

Authors
CHEN A SCHULLERY SE SCOTT RM
Citation
A. Chen et al., SHORT-RANGE SOLVATION OF PROTON-TRANSFER COMPLEXES BY 2,2-DIMETHYL-1,3-DIOXANE AND TRIOXANE, Journal of molecular structure, 322, 1994, pp. 321-327
Citations number
20
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
322
Year of publication
1994
Pages
321 - 327
Database
ISI
SICI code
0022-2860(1994)322:<321:SSOPCB>2.0.ZU;2-O
Abstract
Bifurcated hydrogen bonds are involved in the short range solvation of amines by electron donating solvents. Further, six-membered ring cycl ic diethers involve interaction of both oxygens of the diether with th e amine proton. We report the expansion of these results to include 2, 2-dimethyl-1,3-dioxane and trioxane. The results suggest that the latt er is involved in a trifurcated hydrogen bond.