NOVEL TYPES OF HYDROGEN-BONDS INVOLVING TRANSITION-METAL ATOMS AND PROTON-TRANSFER (XH...M, [MH]-)(...B, [MH]+...A)

Authors
EPSTEIN LM KRYLOV AN SHUBINA ES
Citation
Lm. Epstein et al., NOVEL TYPES OF HYDROGEN-BONDS INVOLVING TRANSITION-METAL ATOMS AND PROTON-TRANSFER (XH...M, [MH]-)(...B, [MH]+...A), Journal of molecular structure, 322, 1994, pp. 345-352
Citations number
27
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
322
Year of publication
1994
Pages
345 - 352
Database
ISI
SICI code
0022-2860(1994)322:<345:NTOHIT>2.0.ZU;2-H
Abstract
The conditions governing the formation of hydrogen bonding involving t ransition metal atoms of the molecular, ion molecular and ionic types in low polar media were found. IR and UV-Vis spectral characteristics of these bonds were determined. Similarities between the spectral prop erties of hydrogen bonds with a metal atom and with common organic bas es as well as some particular characteristics of the former were estab lished. The equilibrium between molecular (OH...M) and ionic (O-...[HM ]-) hydrogen-bonded complexes was investigated.