Ms. Pindzola et al., TIME-DEPENDENT AND TIME-INDEPENDENT CLOSE-COUPLING METHODS FOR THE ELECTRON-IMPACT IONIZATION OF BE+, Physical review. A, 56(3), 1997, pp. 1994-1999
The electron-impact ionization cross section of Be+ is calculated usin
g both a time-dependent and a time-independent close-coupling method.
The time-dependent method is based on the propagation of wave packets
constructed using excited-state orbitals calculated in a core pseudopo
tential. The time-independent method is an R-matrix solution based on
a total wave function constructed using antisymmetrized products of La
guerre pseudo-orbitals and zero-derivative box orbitals. in both metho
ds, low partial-wave close-coupling results are added to high partial-
wave distorted-wave results to yield ionization cross sections for Be substantially below the experimental crossed-beam measurements of Fal
k and Dunn [Phys. Rev. A 27, 754 (1983)] and in agreement with the rec
ent time-independent close-coupling calculations of Bartschat and Bray
[J. Phys. B 30, L109 (1997)].