Photoactive TiO2 surface layers were prepared by the sol-gel process.
Their photoelectric activities were judged from measured effective qua
ntum yields of photocurrent. It was found that the photoelectrochemica
l deposition of o-toluidine, pyrrole, and aniline takes place on these
surface layers. Changes of hydrophilic-hydrophobic surface nature acc
ompanied with the photoelectrochemical deposition of organic layers we
re evaluated by measuring contact angle of water drop.