MATHEMATICAL-MODEL FOR RECHARGEABLE REDOX BATTERIES BASED ON ZINC-FERRICYANIDE

Authors
KOSHEL ND ZVYCHAINYI VG
Citation
Nd. Koshel et Vg. Zvychainyi, MATHEMATICAL-MODEL FOR RECHARGEABLE REDOX BATTERIES BASED ON ZINC-FERRICYANIDE, Russian journal of electrochemistry, 33(8), 1997, pp. 904-909
Citations number
10
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
33
Issue
8
Year of publication
1997
Pages
904 - 909
Database
ISI
SICI code
1023-1935(1997)33:8<904:MFRRBB>2.0.ZU;2-D
Abstract
A mathematical model is proposed for rechargeable redox batteries base d on the Zn-K3Fe(CN)(6) system. The kinetic regularities governing the principal and side electrochemical processes and the transport proces ses are described by empirical functions. A unit element of the batter y is considered as a system with distributed parameters whose state va ries continuously in successive charge and discharge cycles conducted at a constant voltage. Relationships between the kinetic characteristi cs of partial processes in the course of cycling are discussed.