SYNTHESIS OF 5(10-]9)ABEO-ERGOLINES

Citation
S. Mantegani et al., SYNTHESIS OF 5(10-]9)ABEO-ERGOLINES, Heterocycles, 45(8), 1997, pp. 1493-1507
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
03855414
Volume
45
Issue
8
Year of publication
1997
Pages
1493 - 1507
Database
ISI
SICI code
0385-5414(1997)45:8<1493:SO5>2.0.ZU;2-R
Abstract
Reaction of the (5 R, 8 R)-ergoline derivative (6) with the couple CCl 4/(Ph)(3)P unexpectedly resulted in the formation of the novel (5 S, 8 R)-5 (10-->9)abeo-ergoline derivative. A mechanism of this transposit ion process is proposed.