REACTION OF PHOSPHAACETYLENES BU(T)CP AND 1-ADCP WITH (PHSE)(2)-XEF2 - FIRST EXAMPLES OF VICINAL BIS-SELENENYLATION (AT P AND C) TO FORM NOVEL PHOSPHAALKENES

Authors
LAALI KK FIEDLER W REGITZ M
Citation
Kk. Laali et al., REACTION OF PHOSPHAACETYLENES BU(T)CP AND 1-ADCP WITH (PHSE)(2)-XEF2 - FIRST EXAMPLES OF VICINAL BIS-SELENENYLATION (AT P AND C) TO FORM NOVEL PHOSPHAALKENES, Chemical communications, (17), 1997, pp. 1641-1642
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1997
Pages
1641 - 1642
Database
ISI
SICI code
1359-7345(1997):17<1641:ROPBA1>2.0.ZU;2-4
Abstract
tert-Butyl- and 1-adamantyl-phosphaacetylenes (2 equiv.) react with (P hSe)(2)-XeFa(2)(--> 2 PhSeF) to give novel phosphaalkenes by vicinal b is-phenylselenenylation (at P and C), in contrast to acetylenes which undergo fluoroselenenylation.