RUTHENIUM(II) AMMINE CENTERS AS EFFICIENT ELECTRON-DONOR GROUPS FOR QUADRATIC NONLINEAR OPTICS

Authors
COE BJ ESSEXLOPRESTI JP HARRIS JA HOUBRECHTS S PERSOONS A
Citation
Bj. Coe et al., RUTHENIUM(II) AMMINE CENTERS AS EFFICIENT ELECTRON-DONOR GROUPS FOR QUADRATIC NONLINEAR OPTICS, Chemical communications, (17), 1997, pp. 1645-1646
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
17
Year of publication
1997
Pages
1645 - 1646
Database
ISI
SICI code
1359-7345(1997):17<1645:RACAEE>2.0.ZU;2-F
Abstract
Ruthenium(II) complex salts trans-[Ru(NH3)(4)(L-D)- (L-A)][PF6](3) (L- D = an N-donor ligand, L-A = a 4,4'-bipyridinium ligand) exhibit large , tunable static first hyperpolarizabilities beta(o) which are associa ted with intense, visible metal-to-ligand charge-transfer excitations.