A DIFFERENT STORY OF BENZENE

Citation
S. Shaik et al., A DIFFERENT STORY OF BENZENE, Journal of molecular structure. Theochem, 398, 1997, pp. 155-167
Citations number
54
Categorie Soggetti
Chemistry Physical
ISSN journal
01661280
Volume
398
Year of publication
1997
Pages
155 - 167
Database
ISI
SICI code
0166-1280(1997)398:<155:ADSOB>2.0.ZU;2-S
Abstract
The paper summarizes a collaborative research of the authors over more than a decade, as described by the speaker (S. Shaik) at the recent W ATOC conference in Jerusalem during July 8-12, 1996. This is a story o f the attempts of the authors to drive home the idea that the pi-elect ronic component of benzene and other conjugated systems has a dual cha racter. The pi-component is, on the one hand, distortive along a local izing mode, and on the other hand, it is stabilized by resonance energ y relative to a localized reference. The text of the paper-is a modifi ed transcript of the talk and as such, the paper conserves the active voice of the speaker S. Shaik and the personalized style of his talk. (C) 1997 Elsevier Science B.V.