SYNTHESIS AND DIELS-ALDER REACTIONS OF 3-METHYLENE-2-FERROCENYLMETHYLENEQUINUCLIDINE

Authors
GARCIA MM PEREZ GE OCHOA FL CRUZALMANZA R
Citation
Mm. Garcia et al., SYNTHESIS AND DIELS-ALDER REACTIONS OF 3-METHYLENE-2-FERROCENYLMETHYLENEQUINUCLIDINE, Tetrahedron, 53(37), 1997, pp. 12369-12376
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
37
Year of publication
1997
Pages
12369 - 12376
Database
ISI
SICI code
0040-4020(1997)53:37<12369:SADRO3>2.0.ZU;2-8
Abstract
The synthesis and chemical reactivity in Diels-Alder reactions of the title compound 6 is described. When 6 was reacted with N-phenylmaleimi de, a 3.1 mixture of isomers exo 14a and endo 14b was found, while wit h triazolinedione 13, a novel ferrocenyl heterocycle 15 was formed. Th e structures for 14b and 15 were confirmed by X-ray diffraction analys is. (C) 1997 Elsevier Science Ltd.