CARBAMATE DERIVED STABLE PRECURSORS FOR GENERATING CHIRAL AZOMETHINE YLIDS UNDER MILD CONDITIONS

Authors
ALKER D HARWOOD LM WILLIAMS CE
Citation
D. Alker et al., CARBAMATE DERIVED STABLE PRECURSORS FOR GENERATING CHIRAL AZOMETHINE YLIDS UNDER MILD CONDITIONS, Tetrahedron, 53(37), 1997, pp. 12671-12678
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
37
Year of publication
1997
Pages
12671 - 12678
Database
ISI
SICI code
0040-4020(1997)53:37<12671:CDSPFG>2.0.ZU;2-F
Abstract
We describe the evolution of stable azomethine ylid precursors which a void the need for an aldehyde in the ylid generation step. tert-Butyl carbamate derivative (16) demonstrates comparable efficiency to the st andard method of ylid generation and trapping, but permits use of mild er conditions. (C) 1997 Elsevier Science Ltd.