SINGLE-ELECTRON PROCESSES IN THE REACTIONS OF INITIATION OF CARBOCATIONIC OLEFIN POLYMERIZATION AND CATALYTIC DEGRADATION OF SATURATED POLYOLEFINS UNDER THE ACTION OF STRONG LEWIS-ACIDS

Citation
Fr. Khalafov et Ba. Krentsel, SINGLE-ELECTRON PROCESSES IN THE REACTIONS OF INITIATION OF CARBOCATIONIC OLEFIN POLYMERIZATION AND CATALYTIC DEGRADATION OF SATURATED POLYOLEFINS UNDER THE ACTION OF STRONG LEWIS-ACIDS, Vysokomolekularnye soedinenia. Seria A, 39(7), 1997, pp. 1140-1145
Citations number
25
Categorie Soggetti
Polymer Sciences
ISSN journal
05075475
Volume
39
Issue
7
Year of publication
1997
Pages
1140 - 1145
Database
ISI
SICI code
0507-5475(1997)39:7<1140:SPITRO>2.0.ZU;2-#
Abstract
The data on the reactions of initiation of carbocationic olefin polyme rization and catalytic degradation of saturated polyolefins under the action of Lewis acids are considered and summarized. The new catalytic properties of strong Lewis acids, which imply their ability to initia te the above processes according to the single-electron transfer mecha nism (direct initiation) with generation of ion-radical and radical ac tive centers, were discovered.