Tm. Birshtein et al., PHASE-DIAGRAM OF A POLYELECTROLYTE BRUSH CONSISTING OF POLYMER-CHAINSWITH CHARGES ON FREE ENDS, Vysokomolekularnye soedinenia. Seria A, 39(7), 1997, pp. 1186-1192
The scaling approach is employed to construct the phase diagram of a p
olyelectrolyte brush with charges on the free ends of grafted chains.
It is shown that the phase diagram under consideration almost coincide
s with that of a brush formed by chains with distributed charge. The r
ole of distribution of the free ends along the brush height is discuss
ed.