PREDICTION OF RETENTION BEHAVIOR OF FERROCENE DERIVATIVES IN SUPERCRITICAL-FLUID CHROMATOGRAPHY

Authors
BRAUER RD BITTERWOLF TE SMART NG BURFORD MD WAI CM
Citation
Rd. Brauer et al., PREDICTION OF RETENTION BEHAVIOR OF FERROCENE DERIVATIVES IN SUPERCRITICAL-FLUID CHROMATOGRAPHY, Analytica chimica acta, 349(1-3), 1997, pp. 239-244
Citations number
23
Categorie Soggetti
Chemistry Analytical
Journal title
Analytica chimica acta → ACNP
ISSN journal
00032670
Volume
349
Issue
1-3
Year of publication
1997
Pages
239 - 244
Database
ISI
SICI code
0003-2670(1997)349:1-3<239:PORBOF>2.0.ZU;2-G
Abstract
The retention behavior in capillary supercritical fluid chromatography (SFC) of a range of ferrocene derivatives is demonstrated. Prediction of retention times and hence elution order of the ferrocene derivativ es based on a knowledge of solute molar volume, solute solubility para meter and the physical parameters of the chromatography column system is shown to be feasible using this procedure.